Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
CAS: 199684-47-4
Molecular Formula: C90H76Cl5NP4Ru2
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) - Names and Identifiers
| Name | Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) |
| Synonyms | (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2] [NH2ME2][(RUCL((R)-BINAP))2(Μ-CL)3] [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3] -binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R) Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II) Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3] DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3] |
| CAS | 199684-47-4 |
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) - Physico-chemical Properties
| Molecular Formula | C90H76Cl5NP4Ru2 |
| Molar Mass | 1674.89 |
| Melting Point | >100°C |
| Appearance | Powder |
| Color | orange |
| Storage Condition | 2-8°C |
| Sensitive | air sensitive |
| MDL | MFCD09753033 |
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) - Risk and Safety
| WGK Germany | 3 |
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) - Introduction
(mu-chloro)bis[(R)-( )-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) is an organometallic compound, the chemical formula is[(R)-( )-BDP] -2rucl-2, where BDP represents 2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl.
Nature:
1. Appearance: It is a yellow crystal or powder.
2. Thermal stability: Under inert atmosphere, it can be stable at high temperature.
3. Solubility: soluble in some organic solvents, such as chlorinated hydrocarbons, aromatic hydrocarbons.
Use:
1. Catalyst: dimethyldichlorotribisphosphine ruthenium catalyst has high catalytic activity and selectivity in asymmetric hydrogenation reaction.
2. Synthesis of organic compounds: It can be used to synthesize some chiral organic compounds, such as chiral alcohols and chiral ketones.
Method:
Through dimethyldichloro Tris (μ-chloro) diphenylphosphine diruthenium (II) and (R)-( )-2,2 '-bis (diphenylphosphino)-1,1'-Binaphthyl reaction preparation. The reaction can be carried out under the protection of anhydrous xenon gas at a suitable temperature.
[(R)-( )-BDP]_2RuCl_2 Cl_2Ru(PPh_3)_2 → [(R)-( )-BDP]_2RuCl_2
Safety Information:
The compound has certain toxicity and should follow safe operating procedures when used. Avoid contact with skin and eyes. Appropriate personal protective equipment, such as laboratory gloves and goggles, should be worn when handling the compound.
Nature:
1. Appearance: It is a yellow crystal or powder.
2. Thermal stability: Under inert atmosphere, it can be stable at high temperature.
3. Solubility: soluble in some organic solvents, such as chlorinated hydrocarbons, aromatic hydrocarbons.
Use:
1. Catalyst: dimethyldichlorotribisphosphine ruthenium catalyst has high catalytic activity and selectivity in asymmetric hydrogenation reaction.
2. Synthesis of organic compounds: It can be used to synthesize some chiral organic compounds, such as chiral alcohols and chiral ketones.
Method:
Through dimethyldichloro Tris (μ-chloro) diphenylphosphine diruthenium (II) and (R)-( )-2,2 '-bis (diphenylphosphino)-1,1'-Binaphthyl reaction preparation. The reaction can be carried out under the protection of anhydrous xenon gas at a suitable temperature.
[(R)-( )-BDP]_2RuCl_2 Cl_2Ru(PPh_3)_2 → [(R)-( )-BDP]_2RuCl_2
Safety Information:
The compound has certain toxicity and should follow safe operating procedures when used. Avoid contact with skin and eyes. Appropriate personal protective equipment, such as laboratory gloves and goggles, should be worn when handling the compound.
Last Update：2024-04-10 22:29:15
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Spot supply
Product Name: [NH2Me2][(RuCl((R)-binap))2(mu-Cl)3] Visit Supplier Webpage Request for quotationCAS: 199684-47-4
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Spot supply
Product Name: [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3] Visit Supplier Webpage Request for quotationCAS: 199684-47-4
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
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